Synthesis, structure and magnetic properties of a series of Ln(iii) complexes with radical-anionic iminopyridine ligands: effect of lanthanide ions on the slow relaxation of the magnetization.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt00738e
Abstract: We report the investigation of synthesis, structure and magnetic properties of a series of homoleptic Ln(iii) complexes coordinated by radical-anionic iminopyridine ligands of general formula [Ln(IPy)3]·solv (IPy = iminopyridine; Ln = Tb, Dy, Er, Y,… read more here.
Keywords: magnetic properties; iii complexes; synthesis structure; structure magnetic ... See more keywords
π-Stacks of radical-anionic naphthalenediimides in a metal-organic framework
Sign Up to like & getrecommendations! Published in 2022 at "Science Advances"
DOI: 10.1126/sciadv.ade1383
Abstract: Radical-ionic metal-organic frameworks (MOFs) have unique optical, magnetic, and electronic properties. These radical ions, forcibly formed by external stimulus-induced redox processes, are structurally unstable and have short radical lifetimes. Here, we report two naphthalenediimide-based (NDI-based)… read more here.
Keywords: dgist; anionic naphthalenediimides; metal organic; stacks radical ... See more keywords