Photoinduced emissive naphthalenediimide radical anion in the confinement of cucurbituril nanocavity; in situ generation of gold nanoparticles
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Molecular Liquids"
DOI: 10.1016/j.molliq.2021.116023
Abstract: Abstract Supramolecularly assembled building blocks, especially those based on π stacked organic or inorganic redox active materials have found encouraging applications in recent years due to their electron-accepting nature and easy structural manipulations. In this… read more here.
Keywords: radical anions; generation; photoinduced emissive; cb7 cb8 ... See more keywords
Dimerized p-Semiquinone Radical Anions Stabilized by a Pair of Rare-Earth Metal Ions.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c00503
Abstract: Here we report stable p-quinone-radical-bridged rare-earth complexes involving the ligand tetramethylquinone (QMe4•-). The complexes, {Y[(QMe4)•-Cl2(THF)3]}2 (1) and {Gd[(QMe4)•-Cl2(THF)3]}2 (2), where THF = tetrahydrofuran, are sufficiently stable that we can measure the single-crystal structures and perform… read more here.
Keywords: radical anions; rare earth; dimerized semiquinone; earth ... See more keywords
In Situ Hypoxia-Induced Supramolecular Perylene Diimide Radical Anions in Tumors for Photothermal Therapy with Improved Specificity.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c13067
Abstract: Considering that hypoxia is closely associated with tumor proliferation, invasion, metastasis, and drug resistance, it is of great significance to overcome hypoxia in tumor treatment. Herein, we report a hypoxia-induced specific photothermal therapy (PTT) based… read more here.
Keywords: hypoxia induced; radical anions; perylene diimide; diimide radical ... See more keywords
A combined experimental and theoretical study on the reactivity of nitrenes and nitrene radical anions
Sign Up to like & getrecommendations! Published in 2022 at "Nature Communications"
DOI: 10.1038/s41467-021-27687-6
Abstract: Nitrene transfer reactions represent one of the key reactions to rapidly construct new carbon-nitrogen bonds and typically require transition metal catalysts to control the reactivity of the pivotal nitrene intermediate. Herein, we report on the… read more here.
Keywords: radical anions; nitrenes nitrene; reactivity; nitrene radical ... See more keywords
The role of polysulfide dianions and radical anions in the chemical, physical and biological sciences, including sulfur-based batteries.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical Society reviews"
DOI: 10.1039/c8cs00826d
Abstract: The well-known tendency of sulfur to catenate is exemplified by an extensive series of polysulfide dianions [Sn]2- (n = 2-9) and related radical monoanions [Sn]˙-. The dianions can be isolated as crystalline salts with appropriate… read more here.
Keywords: radical anions; chemistry; dianions radical; polysulfide dianions ... See more keywords
Enhanced photothermal performance of graphene oxide by perylene diimide radical anions /α-phenylethylamine hydeogen bonded complex embedded in graphene oxide films for solar water evaporation
Sign Up to like & getrecommendations! Published in 2023 at "New Journal of Chemistry"
DOI: 10.1039/d3nj01145c
Abstract: Typically, perylene diimide radical anions have broad and strong absorption in the near-infrared light region and excellent photothermal conversion performance, so they are considered as new potential organic photothermal materials.... read more here.
Keywords: graphene; radical anions; diimide radical; graphene oxide ... See more keywords
Unprecedented intact radical anions, closed shell anions, cluster ions, and traditional cations and radical cations by LIFDI–MS
Sign Up to like & getrecommendations! Published in 2023 at "European Journal of Mass Spectrometry"
DOI: 10.1177/14690667221146079
Abstract: Liquid injection field desorption ionization (LIFDI) proves the extraordinary softness of the ionization process combined with a convenient sample supply under the exclusion of moisture and air. LIFDI–mass spectrometry (MS) is used for organometallic and… read more here.
Keywords: intact radical; radical anions; unprecedented intact; closed shell ... See more keywords
Chemical doping of unsubstituted perylene diimide to create radical anions with enhanced stability and tunable photothermal conversion efficiency
Sign Up to like & getrecommendations! Published in 2023 at "Frontiers in Chemistry"
DOI: 10.3389/fchem.2023.1187378
Abstract: N-doping of perylene diimides (PDIs) to create stable radical anions is significant for harvesting photothermal energy due to their intensive absorption in the near-infrared (NIR) region and non-fluorescence. In this work, a facile and straightforward… read more here.
Keywords: radical anions; create radical; diimide create; perylene diimide ... See more keywords