Redox Control of Radical‐Based Dynamic Covalent Chemistry: Macrocycle Formation and Electrochemical Deoligomerization of Bis(Dicyanomethyl Radical)‐Substituted Ferrocene
Sign Up to like & getrecommendations! Published in 2025 at "Asian Journal of Organic Chemistry"
DOI: 10.1002/ajoc.202500253
Abstract: Dicyanomethyl radicals conjugated with electron donors have attracted renewed interest as building blocks in radical‐based dynamic covalent chemistry (DCC). In this study, we prepared a novel diradical exhibiting DCC properties, composed of two dicyanomethyl radicals… read more here.
Keywords: based dynamic; chemistry; covalent chemistry; dynamic covalent ... See more keywords
Hierarchical collagen fibers complexed with tannic acid and Fe3+ as a heterogeneous catalyst for enhancing sulfate radical-based advanced oxidation process
Sign Up to like & getrecommendations! Published in 2022 at "Environmental Science and Pollution Research"
DOI: 10.1007/s11356-022-19907-3
Abstract: Efficient sulfate radical-based advanced oxidation processes (SR-AOPs) are important for treating organic contaminants of industrial wastewater. To achieve this goal, tannic acid (TA)–modified skin collagen fibers (CFs) were prepared for the enhanced immobilization of Fe3+… read more here.
Keywords: heterogeneous catalyst; based advanced; catalyst; radical based ... See more keywords
The application of sulfate radical-based advanced oxidation processes in hydrothermal treatment of activated sludge at different stages: A comparative study
Sign Up to like & getrecommendations! Published in 2022 at "Environmental Science and Pollution Research"
DOI: 10.1007/s11356-022-20038-y
Abstract: Integrating hydrothermal treatment (HT) and advanced oxidation processes (AOP) was proved to be a promising approach for improving sludge dewaterability. In this study, the EPS valorization under elevated temperature and sulfate radical-based AOP were investigated… read more here.
Keywords: oxidation processes; radical based; hydrothermal treatment; advanced oxidation ... See more keywords
Thiyl Radical-Based Charge Tagging Enables Sterol Quantitation via Mass Spectrometry.
Sign Up to like & getrecommendations! Published in 2017 at "Analytical chemistry"
DOI: 10.1021/acs.analchem.7b04080
Abstract: Inspired by the high reactivity and specificity of thiyl radicals toward alkenes, we have developed a new charge derivatization method to enable fast and quantitative analysis of sterols via electrospray ionization-mass spectrometry (ESI-MS). Thioglycolic acid… read more here.
Keywords: mass spectrometry; thiyl radical; charge tagging; charge ... See more keywords
Glycosyl Radical-Based C-H Glycosylation of Coumarins Enabled by Photocatalysis.
Sign Up to like & getrecommendations! Published in 2025 at "Organic letters"
DOI: 10.1021/acs.orglett.5c04327
Abstract: We report the photocatalytic C-H glycosylation of coumarins with glycosyl radicals. This transformation employs an organic photosensitizer and proceeds under mild conditions in the presence of a weak acid. The reaction exhibits α-selectivity with pyranohexose-derived… read more here.
Keywords: coumarins enabled; glycosyl radical; based glycosylation; glycosylation coumarins ... See more keywords
Twofold Radical-Based Synthesis of N,C-Difunctionalized Bicyclo[1.1.1]pentanes.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c04180
Abstract: Bicyclo[1.1.1]pentylamines (BCPAs) are of growing importance to the pharmaceutical industry as sp3-rich bioisosteres of anilines and N-tert-butyl groups. Here we report a facile synthesis of 1,3-disubstituted BCPAs using a twofold radical functionalization strategy. Sulfonamidyl radicals,… read more here.
Keywords: twofold radical; based synthesis; synthesis difunctionalized; bicyclo ... See more keywords
Efficient radical-based light-emitting diodes with doublet emission
Sign Up to like & getrecommendations! Published in 2018 at "Nature"
DOI: 10.1038/s41586-018-0695-9
Abstract: Organic light-emitting diodes (OLEDs)1–5, quantum-dot-based LEDs6–10, perovskite-based LEDs11–13 and micro-LEDs14,15 have been championed to fabricate lightweight and flexible units for next-generation displays and active lighting. Although there are already some high-end commercial products based on OLEDs,… read more here.
Keywords: doublet; emitting diodes; light emitting; radical based ... See more keywords