Reductive Radical Cascades Triggered by Alkoxyl Radicals in the β-Cyclodextrin Framework.
Sign Up to like & getrecommendations! Published in 2018 at "Organic letters"
DOI: 10.1021/acs.orglett.8b01308
Abstract: The generation and fate of 2I-VII,3I-VII,6II-VII-icosa- O-methyl-β-cyclomaltoheptaos-6I- O-yl radical under reductive conditions is described. Two radical cascade reactions are involved: the main one is triggered by a 1,8-HAT of the hydrogen at 5VIIC. The radical… read more here.
Keywords: radicals cyclodextrin; radical cascades; reductive radical; triggered alkoxyl ... See more keywords
General method for iron-catalyzed multicomponent radical cascades–cross-couplings
Sign Up to like & getrecommendations! Published in 2021 at "Science"
DOI: 10.1126/science.abj6005
Abstract: Description Iron links a trio Iron holds particular appeal as a catalytic metal—it is safe and abundant, as well as a mainstay of enzymatic reactivity. Nonetheless, in synthetic construction of carbon-carbon bonds, modern chemists have… read more here.
Keywords: cross couplings; carbon; radical cascades; carbon carbon ... See more keywords