Synthesis and Crystal Structures of Two Metal–Radical Complexes
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Chemical Crystallography"
DOI: 10.1007/s10870-019-00797-2
Abstract: Two new M(II)–radical complexes [M(hfac)2(NITPhSCH3)2] (M = Co (1), Mn (2); NITPhSCH3 = 4′-thiomethylphenyl-4,4,5,5-tetramethyl-imidazoline-1-oxyl-3-oxide; and hfac = hexafluoroacetylacetonate) have been synthesized and characterized by X-ray diffraction analysis, element analyses, IR and UV–Visible spectroscopy. X-ray analysis reveals that the structures of both… read more here.
Keywords: two metal; structures two; metal radical; crystal structures ... See more keywords
Highly durable photochromic radical complexes having no steric protections of radicals.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c7cc01439b
Abstract: Steric protection groups are usually necessary for stable radicals. However, here, we developed novel photochromic radical complexes which generate sterically unprotected imidazolyl and phenoxyl radicals upon UV light irradiation based on the phenoxyl-imidazolyl radical complex… read more here.
Keywords: complexes steric; highly durable; photochromic radical; radical complexes ... See more keywords
π–π Stacking Interaction of Metal Phenoxyl Radical Complexes
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DOI: 10.3390/molecules27031135
Abstract: π–π stacking interaction is well-known to be one of the weak interactions. Its importance in the stabilization of protein structures and functionalization has been reported for various systems. We have focused on a single copper… read more here.
Keywords: metal phenoxyl; interaction metal; phenoxyl radical; interaction ... See more keywords