Degradable Alternating Copolymers by Radical Copolymerization of 2-Methylen-1,3-dioxepane and Crotonate Esters
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DOI: 10.1021/acsmacrolett.4c00101
Abstract: Producing backbone degradable copolymers via free-radical copolymerization is a promising, yet challenging method to develop more sustainable materials for many applications. In this work, we present the copolymerization of 2-methylen-1,3-dioxepane (MDO) with crotonic acid derivative… read more here.
Keywords: copolymerization methylen; methylen dioxepane; alternating copolymers; radical copolymerization ... See more keywords
Preparation of Microporous Organic Polymers via UV-Initiated Radical Copolymerization
Sign Up to like & getrecommendations! Published in 2018 at "ACS Macro Letters"
DOI: 10.1021/acsmacrolett.8b00688
Abstract: UV-initiated radical copolymerization has been successfully applied for the preparation of two kinds of microporous organic polymers (MOPs) based on divinylbenzene (DVB)/bismaleimide (BMI) monomers... read more here.
Keywords: organic polymers; microporous organic; initiated radical; preparation microporous ... See more keywords
Synthetic access to an elusive high-temperature perfluoroisopropenyl ether prepolymer for radical copolymerization.
Sign Up to like & getrecommendations! Published in 2018 at "Chemical communications"
DOI: 10.1039/c8cc05241g
Abstract: A perfluoroisopropenyl ether terminated oligo(hexafluoropropylene oxide), a perfluoropolyalkyl ether macromonomer for radical copolymerization, has been prepared. The synthesis was achieved through a carefully controlled defluorination of a highly unstable lithium perfluorocarbanion intermediate. Several undesired pathways… read more here.
Keywords: synthetic access; radical copolymerization; perfluoroisopropenyl ether; access elusive ... See more keywords
Hydrophilic bio-based polymers by radical copolymerization of cyclic vinyl ethers derived from glycerol.
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DOI: 10.1039/d2cc02651a
Abstract: In this study, novel functional polymers were obtained by using glycerol as a bio-based precursor, which is abundant and inexpensive renewable feedstock with a polyol skeleton. Cyclic vinyl ethers with acetal linkage were derived from… read more here.
Keywords: derived glycerol; vinyl; vinyl ethers; cyclic vinyl ... See more keywords
Comparison of gels synthesized by controlled radical copolymerization and free radical copolymerization: molecular dynamics simulation.
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DOI: 10.1039/d3sm01431b
Abstract: The structures of gels synthesized by controlled radical copolymerization (CRP) and conventional free radical copolymerization (FRP) were studied by a coarse-grained molecular dynamics simulation. It was confirmed that the CRP gel has a larger number… read more here.
Keywords: gels synthesized; gel; synthesized controlled; radical copolymerization ... See more keywords
Free radical copolymerization of 1,3-cyclooctadiene with maleic anhydride or N-substituted maleimides: a simple way to obtain high-performance transparent plastics.
Sign Up to like & getrecommendations! Published in 2024 at "Chemical communications"
DOI: 10.1039/d4cc05100a
Abstract: Herein, we report the free radical copolymerization of 1,3-cyclooctadiene and maleic anhydride or N-substituted maleimides. The obtained alternating copolymers have a fine-tuned Tg (ranging from 62 °C to 300 °C) and excellent thermal resistance and… read more here.
Keywords: radical copolymerization; cyclooctadiene maleic; maleic anhydride; anhydride substituted ... See more keywords