Highly Selective Intermolecular Cross-Coupling Reactions via a Persistent Radical Effect on Ag(111).
Sign Up to like & getrecommendations! Published in 2025 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.5c13021
Abstract: Achieving highly selective cross-coupling between two radicals remains a long-standing challenge due to competing homocoupling pathways. Here, we report a high-yield radical-based cross-coupling reaction on Ag(111), enabled by the persistent radical effect. Using bond-resolving scanning… read more here.
Keywords: persistent radical; cross coupling; highly selective; radical effect ... See more keywords
Exploring frustrated radical pairs through the persistent radical effect: methods of generation and recent applications.
Sign Up to like & getrecommendations! Published in 2025 at "Chemical communications"
DOI: 10.1039/d5cc00946d
Abstract: Radicals have long fascinated chemists owing to their structure, reactivity, and other features. The recent discovery of frustrated radical pairs (FRPs) has added a new dimension to this field. These unique radicals, which do not… read more here.
Keywords: persistent radical; frustrated radical; exploring frustrated; radical pairs ... See more keywords