Tertiary Amines Acting as Alkyl Radical Equivalents Enabled by a P/N Heteroleptic Cu(I) Photosensitizer.
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DOI: 10.1021/acs.orglett.0c03236
Abstract: An unprecedented exploration of tertiary amines as alkyl radical equivalents for cross-coupling with aromatic alkynes to access allylarenes has been achieved by a P/N heteroleptic Cu(I)-based photosensitizer under photoredox catalysis conditions. Mechanistic studies reveal that… read more here.
Keywords: tertiary amines; acting alkyl; radical equivalents; alkyl radical ... See more keywords