Iron-Catalyzed Radical Hydrothiolation of gem-Difluoroalkenes.
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DOI: 10.1021/acs.orglett.5c02890
Abstract: gem-Difluoroalkenes serve as versatile intermediates in organofluorine chemistry, offering unique opportunities for synthetic elaboration. Leveraging the distinctive reactivity profile of gem-difluoroalkenes, we disclose herein an iron-catalyzed, regioselective hydrothiolation protocol that affords a diverse array of… read more here.
Keywords: gem difluoroalkenes; catalyzed radical; radical hydrothiolation; gem ... See more keywords