Novel thermal radical initiators based on a triazene moiety for radical polymerization
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Industrial and Engineering Chemistry"
DOI: 10.1016/j.jiec.2018.08.008
Abstract: Abstract In this study, we designed and synthesized novel thermal radical initiators of BTAP (1-phenyl-3,3-dipropyltriazene), BTACP (1-(phenyldiazenyl)pyrrolidine), BTACH (1-(phenyldiazenyl)piperidine), and BTACH7 (1-(phenyldiazenyl)azepane) based on a triazene moiety to provide a thermal initiator for radical polymerization.… read more here.
Keywords: thermal radical; radical initiators; polymerization; radical polymerization ... See more keywords
Site-selective radical reactions of kinetically stable open-shell singlet diradicaloid difluorenoheteroles with tributyltin hydride and azo-based radical initiators
Sign Up to like & getrecommendations! Published in 2023 at "Chemical Science"
DOI: 10.1039/d3sc00381g
Abstract: We have demonstrated site-selective radical reactions of the kinetically stable open-shell singlet diradicaloids difluoreno[3,4-b:4′,3′-d]thiophene (DFTh) and difluoreno[3,4-b:4′,3′-d]furan (DFFu) with tributyltin hydride (HSn(n-Bu)3) and azo-based radical initiators. Treatment of these diradicaloids with HSn(n-Bu)3 induces hydrogenation at… read more here.
Keywords: radical initiators; site selective; azo based; radical reactions ... See more keywords