Articles with "radical ligand" as a keyword



Mechanochemistry Drives Alkene Difunctionalization via Radical Ligand Transfer and Electron Catalysis

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Published in 2024 at "Advanced Science"

DOI: 10.1002/advs.202402970

Abstract: A general and modular protocol is reported for olefin difunctionalization through mechanochemistry, facilitated by cooperative radical ligand transfer (RLT) and electron catalysis. Utilizing mechanochemical force and catalytic amounts of 2,2,6,6‐tetramethylpiperidinyloxyl (TEMPO), ferric nitrate can leverage… read more here.

Keywords: radical ligand; mechanochemistry; difunctionalization; electron catalysis ... See more keywords