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Published in 2017 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.6b09892
Abstract: Persistent π-radicals such as MV+• (MV refers to methyl viologen, i.e., N,N'-dimethyl-4,4'-bipyridinum) engage in weak radical-radical interactions. This phenomenon has been utilized recently in supramolecular chemistry with the discovery that MV+• and [cyclobis(paraquat-p-phenylene)]2(+•) (CBPQT2(+•)) form…
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Keywords:
matched radical;
radical multivalency;
radical pairing;
complex cbpqt ... See more keywords