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Published in 2017 at "Biophysical journal"
DOI: 10.1016/j.bpj.2017.07.031
Abstract: The radical-pair mechanism has been put forward as the basis of the magnetic compass sense of migratory birds. Some of the strongest supporting evidence has come from behavioral experiments in which birds exposed to weak…
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Keywords:
radical pair;
magnetic compass;
radiofrequency;
migratory birds ... See more keywords
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Published in 2019 at "Journal of Magnetism and Magnetic Materials"
DOI: 10.1016/j.jmmm.2019.01.099
Abstract: Abstract In this paper, we used anti-cancer flutamide (FM) as a radical pair-forming drug to investigate whether magnetic fields can control a liposomal drug release through differences in the physical properties of biomembranes. Irradiations of…
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Keywords:
radical pair;
system;
pair;
drug ... See more keywords
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Published in 2018 at "Journal of Photochemistry and Photobiology A: Chemistry"
DOI: 10.1016/j.jphotochem.2018.06.014
Abstract: Abstract Photo-Fries rearrangement of phenyl benzoate is studied using continuous flow for modulating the reactivity of singlet radical pair by changing the viscosity of the solvent. The effect of flow and proximity of the reactants…
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Keywords:
radical pair;
fries rearrangement;
photo fries;
reactivity ... See more keywords
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Published in 2018 at "ACS Catalysis"
DOI: 10.1021/acscatal.8b00120
Abstract: Coenzyme B12 (adenosylcobalamin = AdoCbl)-dependent enzymes catalyze complex molecular transformations by employing radical chemistry. The initial step in the native catalytic cycle, upon substrate binding, involves homolytic cleavage of the Co–C bond of AdoCbl to…
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Keywords:
coenzyme b12;
radical pair;
mechanism;
ethanolamine ammonia ... See more keywords
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Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c13108
Abstract: Activation of inert molecules like CO2 is often mediated by cooperative chemistry between two reactive sites within a catalytic assembly, the most common form of which is Lewis acid/base bifunctionality observed in both natural metalloenzymes…
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Keywords:
radical pair;
cooperative activation;
heterobinuclear complex;
activation co2 ... See more keywords
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Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c01196
Abstract: The generally proposed mechanism for the reaction between non-heme Fe-oxo complexes and alkane C-H bonds involves a hydrogen atom transfer (HAT) reaction step with a radical pair intermediate that then has competitive radical rebound, dissociation,…
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Keywords:
radical pair;
dynamics trajectories;
pair;
direct dynamics ... See more keywords
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Published in 2019 at "Nature Communications"
DOI: 10.1038/s41467-019-11655-2
Abstract: The fact that many animals, including migratory birds, use the Earth’s magnetic field for orientation and compass-navigation is fascinating and puzzling in equal measure. The physical origin of these phenomena has not yet been fully…
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Keywords:
magnetoreception;
radical pair;
chemical compass;
hypothesis ... See more keywords
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Published in 2023 at "Chemical communications"
DOI: 10.1039/d3cc00146f
Abstract: The reactive HO˙/(Salophent-Bu)Co(II) radical pair was observed to be generated via homolysis of the terminal Co(III)-OH bond in transient (Salophent-Bu)(L)Co(III)(OH) (L = Py, MeOH) complexes as indicated by UV-Vis and EPR measurements. Based on this…
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Keywords:
radical pair;
iii;
generated via;
salophent radical ... See more keywords
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Published in 2022 at "Journal of the Royal Society Interface"
DOI: 10.1098/rsif.2022.0325
Abstract: Hundreds of studies have found that weak magnetic fields can significantly influence various biological systems. However, the underlying mechanisms behind these phenomena remain elusive. Remarkably, the magnetic energies implicated in these effects are much smaller…
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Keywords:
radical pair;
field effects;
biology;
pair mechanism ... See more keywords
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Published in 2022 at "Physical review. E"
DOI: 10.1103/physreve.106.064409
Abstract: In this paper, we investigate the effect of chiral-induced spin selectivity (CISS) on the radical pair mechanism of avian magnetoreception. We examine the impact of spin selectivity on the avian compass sensitivity. In this analysis,…
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Keywords:
radical pair;
pair;
sensitivity;
chiral induced ... See more keywords
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Published in 2017 at "Physical review letters"
DOI: 10.1103/physrevlett.118.200402
Abstract: The radical pair reaction underlies the magnetic field sensitivity of chemical reactions and is suggested to play an important role in both chemistry and biology. Current experimental evidence is based on ensemble measurements; however, the…
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Keywords:
pair reaction;
single molecule;
radical pair;
spin diamond ... See more keywords