Size-Matched Radical Multivalency.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.6b09892
Abstract: Persistent π-radicals such as MV+• (MV refers to methyl viologen, i.e., N,N'-dimethyl-4,4'-bipyridinum) engage in weak radical-radical interactions. This phenomenon has been utilized recently in supramolecular chemistry with the discovery that MV+• and [cyclobis(paraquat-p-phenylene)]2(+•) (CBPQT2(+•)) form… read more here.
Keywords: matched radical; radical multivalency; radical pairing; complex cbpqt ... See more keywords
Radical Pairing Interactions and Donor–Acceptor Interactions in Cyclobis(paraquat-p-phenylene) Inclusion Complexes
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DOI: 10.3390/molecules28052057
Abstract: Understanding molecular interactions in mechanically interlocked molecules (MIMs) is challenging because they can be either donor–acceptor interactions or radical pairing interactions, depending on the charge states and multiplicities in the different components of the MIMs.… read more here.
Keywords: pairing interactions; interactions cyclobis; radical pairing; donor acceptor ... See more keywords