From Ambiguity to Application: Deciphering Non-Radical Pathways in Heterogeneous Persulfate Activation.
Sign Up to like & getrecommendations! Published in 2025 at "Advanced materials"
DOI: 10.1002/adma.202516166
Abstract: Non‐radical pathways have emerged as a critical research frontier in persulfate‐based heterogeneous advanced oxidation processes (PS‐HAOPs), offering superior selectivity and thereby resistance to background interference compared to conventional radical‐based routes. However, the practical implementation remains… read more here.
Keywords: ambiguity application; radical pathways; deciphering non; application deciphering ... See more keywords
Introduction of Difluoromethyl through Radical Pathways
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DOI: 10.1002/ejoc.202400423
Abstract: During the past decade, radical difluoromethylation has received much attention and rapid developments for its mild reaction conditions and good functional group compatibilities. A diverse array of difluoromethyl radical precursors and corresponding radical reactions have… read more here.
Keywords: difluoromethyl radical; chemistry; introduction difluoromethyl; radical pathways ... See more keywords
Highly-efficient and Stable MgCo2O4 Spinel for Bisphenol A Removal by Activating Peroxymonosulfate via Radical and Non-radical Pathways
Sign Up to like & getrecommendations! Published in 2021 at "Chemical Engineering Journal"
DOI: 10.1016/j.cej.2021.129498
Abstract: Abstract Nowadays, the limited catalytic efficiency, secondary pollution of metal leaching and stability decrease during reuse bring challenges to practical application of heterogeneous catalysts in sulfate radical-based advanced oxidation processes. Herein, MgCo2O4 spinel was synthesized… read more here.
Keywords: mgco2o4; microscopy; radical pathways; radical non ... See more keywords
Radical pathways for 2,4-chromandione synthesis via photoexcitation of 4-hydroxycoumarins
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DOI: 10.1039/d4sc07495e
Abstract: 4-Hydroxycoumarins are well-known for their ground-state nucleophilic behavior, which has been widely exploited for their functionalization. Herein, we reveal a previously unexplored photochemical reactivity: upon deprotonation and excitation with purple light, 3-substituted 4-hydroxycoumarins reach an… read more here.
Keywords: synthesis via; pathways chromandione; radical pathways; synthesis ... See more keywords
'Green-to-Green': Iron oxides embedded in lignin-based carbon scaffolds for water remediation via oxidation excluding free-radical pathways.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of hazardous materials"
DOI: 10.2139/ssrn.4177712
Abstract: Advanced oxidation processes (AOP) are a common tool to remove organic compounds from the water cycle. The process is mostly relied on free radicals (i.e., SO4•- and HO•) with high oxidation power in solution. Surface-mediated… read more here.
Keywords: oxidation; carbon; iron; water ... See more keywords