Liquid Metals as Initiators of Free‐Radical Polymerization of Hydrogels: A Perspective
Sign Up to like & getrecommendations! Published in 2025 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202514024
Abstract: This perspective article highlights an interesting and useful discovery: gallium‐based liquid metals can initiate free radical polymerization to form hydrogels. Normally, hydrogels are polymerized using molecular initiators that generate radicals in response to heat or… read more here.
Keywords: liquid metal; radical polymerization; metal; free radical ... See more keywords
Trending green atom transfer radical polymerization (ATRP)‐modified lactic acid bacteria: application as a bioadsorbent to detoxicate aflatoxin B1 in grains
Sign Up to like & getrecommendations! Published in 2025 at "Journal of the Science of Food and Agriculture"
DOI: 10.1002/jsfa.14216
Abstract: To address the severe health risks posed by aflatoxin B1 (AFB1) in grain, this study employed polydopamine‐based atom transfer radical polymerization (p‐ATRP) and cytochrome C‐catalyzed atom transfer radical polymerization (c‐ATRP) as cytocompatible modification techniques to… read more here.
Keywords: radical polymerization; polymerization atrp; atom transfer; transfer radical ... See more keywords
Mechanistic Aspects of Aqueous Heterogeneous Radical Polymerization of Styrene under Compressed CO2
Sign Up to like & getrecommendations! Published in 2017 at "Macromolecular Chemistry and Physics"
DOI: 10.1002/macp.201700128
Abstract: Radical polymerization of styrene in aqueous emulsions pressurized by CO2 has been investigated with a view to development of low energy miniemulsion polymerization. The general requirement of high energy mixing to generate miniemulsions comprising sub-micrometer-size… read more here.
Keywords: polymerization; aspects aqueous; polymerization styrene; radical polymerization ... See more keywords
Cobalt–Oxygen Bond Homolysis in the Bench‐Stable (Salen*)Cobalt(III) Acetate Complex: Insight into the Organometallic Mediated Radical Polymerization of Diverse Monomers
Sign Up to like & getrecommendations! Published in 2025 at "Macromolecular Chemistry and Physics"
DOI: 10.1002/macp.202500204
Abstract: Thermal activation of the [(Salen*)CoIII(OAc)] (Salen* = (R,R)‐N, N’‐bis(3,5‐di‐tert‐butylsalicylidene)‐1,2‐cyclohexanediamine) complex (1) allows to initiate the radical polymerization of methyl methacrylate (MMA) and methyl acrylate (MA) via CoIII─O bond homolysis. Catalytic chain‐transfer has been identified as… read more here.
Keywords: bond homolysis; mediated radical; radical polymerization; polymerization ... See more keywords
Surface-Initiated Atom Transfer Radical Polymerization from Electrospun Mats: An Alternative to Nafion
Sign Up to like & getrecommendations! Published in 2017 at "Macromolecular Materials and Engineering"
DOI: 10.1002/mame.201600410
Abstract: Alternative to Nafion DTU Orbit (27/09/2019) Surface-Initiated Atom Transfer Radical Polymerization from Electrospun Mats: An Alternative to Nafion Proton exchange membranes for fuel cell applications are synthesized by surface-initiated(SI) atom transfer radical polymerization (ATRP). Poly(vinylidene… read more here.
Keywords: atom transfer; radical polymerization; transfer radical; initiated atom ... See more keywords
Atom Transfer Radical Polymerization (ATRP) Catalyzed by Visible Light-Absorbed Small Molecule Organic Semiconductors.
Sign Up to like & getrecommendations! Published in 2018 at "Macromolecular rapid communications"
DOI: 10.1002/marc.201800466
Abstract: Atom transfer radical polymerization is successfully conducted with an organic semiconductor (OS)-based visible light activated photocatalyst via a precisely designed catalytic cycle. The living nature of the polymerization by the OS type photocatalyst is proved… read more here.
Keywords: atom transfer; polymerization; radical polymerization; transfer radical ... See more keywords
Fenton-Chemistry-Mediated Radical Polymerization.
Sign Up to like & getrecommendations! Published in 2019 at "Macromolecular rapid communications"
DOI: 10.1002/marc.201900220
Abstract: In this review, the power of a classical chemical reaction, the Fenton reaction for initiating radical polymerizations, is demonstrated. The reaction between the Fenton reagents (i.e., Fe2+ and H2 O2 ) generates highly reactive hydroxyl… read more here.
Keywords: radical polymerization; chemistry; reaction; mediated radical ... See more keywords
Synthesis of High Molecular Weight Polymers by Organocatalyzed Living Radical Polymerization and Self-assembly.
Sign Up to like & getrecommendations! Published in 2023 at "Macromolecular rapid communications"
DOI: 10.1002/marc.202300005
Abstract: A mild organocatalyzed living radical polymerization method was studied for high molecular weight polymers (HMWPs), yielding low-dispersity linear and star polymers (Đ = Mw /Mn = 1.03-1.28) up to Mn = 3.9 × 105 and monomer… read more here.
Keywords: radical polymerization; molecular weight; living radical; high molecular ... See more keywords
Antimony-based Halide Perovskite Nanoparticles as lead-free Photocatalysts for Controlled Radical Polymerization.
Sign Up to like & getrecommendations! Published in 2024 at "Macromolecular rapid communications"
DOI: 10.1002/marc.202300695
Abstract: Metal halide perovskites have emerged as versatile photocatalysts to convert solar energy for chemical processes. Perovskite photocatalyzed polymerization draws special attention due to its straightforward synthesis process and the ability to create advanced perovskite-polymer nanocomposites.… read more here.
Keywords: cs3 sb2; perovskite nanoparticles; radical polymerization; polymerization ... See more keywords
Preparation of One‐Dimensional Polymer Brushes by Atom Transfer Radical Polymerization of Styrene Initiated by Macroinitiator
Sign Up to like & getrecommendations! Published in 2024 at "Polymers for Advanced Technologies"
DOI: 10.1002/pat.70052
Abstract: Reversible deactivation radical polymerization (RDRP) is a controllable technique for free radical polymerization to synthesize polymer brushes. Macroinitiators have the advantage of grafting polymer brushes with high density over small molecule initiators due to the… read more here.
Keywords: polymer brushes; radical polymerization; polymerization; polymer ... See more keywords
Polymericaly modified clays to preparation of polystyrene nanocomposite by nitroxide mediated radical polymerization and solution blending methods
Sign Up to like & getrecommendations! Published in 2017 at "Polymer Composites"
DOI: 10.1002/pc.23675
Abstract: Polymericaly modified clays that contain an oligomeric poly (styrene-co-chloromethyl styrene) ammonium salt have been prepared and used to preparation of polystyrene (PS) nanocomposites. First, PS and poly(styrene-co-chloromethyl styrene) [P(St-co-CMSt)] were synthesized by nitroxide mediated living… read more here.
Keywords: polymericaly modified; preparation polystyrene; radical polymerization; modified clays ... See more keywords