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Published in 2017 at "Biochemistry"
DOI: 10.1021/acs.biochem.7b00294
Abstract: The kinetics of the substrate radical rearrangement reaction step in B12-dependent ethanolamine ammonia-lyase (EAL) from Salmonella typhimurium are measured over a 92 K temperature range. The observed first-order rate constants display a piecewise-continuous Arrhenius dependence,…
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Keywords:
rearrangement reaction;
substrate radical;
radical rearrangement;
reaction ... See more keywords