n Bu4NOTf-promoted radical self-hydrogen transferring isomerization under transition metal-free conditions
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DOI: 10.1039/c7qo01138e
Abstract: We report the first allylic isomerization of alcohols catalyzed by nBu4NOTf generated in situ from tetrabutylammonium triflate and potassium tert-butoxide. Substituted ketones could be prepared under mild conditions in good to excellent yields. The relationship… read more here.
Keywords: promoted radical; radical self; self hydrogen; isomerization ... See more keywords