Dual‐Functioning Molecular Carrier of Superoxide Radicals for Stable and Efficient Lithium–Oxygen Batteries
Sign Up to like & getrecommendations! Published in 2020 at "Advanced Energy Materials"
DOI: 10.1002/aenm.201904187
Abstract: Low round‐trip efficiency and poor cycle stability remain the major challenges associated with lithium–oxygen (Li–O2) batteries. These issues are primarily triggered by or correlated to the radical species produced during the operation of Li–O2 cells,… read more here.
Keywords: superoxide radicals; dual functioning; oxygen; oxygen batteries ... See more keywords
Boron-containing radical species
Sign Up to like & getrecommendations! Published in 2017 at "Coordination Chemistry Reviews"
DOI: 10.1016/j.ccr.2017.09.019
Abstract: Abstract Radicals are ubiquitously involved in numerous chemical and biological processes. They exhibit unique chemical bonding and physical properties applicable to functional materials. With respect to carbon and nitrogen, boron is commonly viewed as a… read more here.
Keywords: containing radical; boron containing; chemistry; radical species ... See more keywords
Mn(iv) and Mn(v)-radical species supported by the redox non-innocent bis(2-amino-3,5-di-tert-butylphenyl)amine pincer ligand.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c7cc00516d
Abstract: The electron-rich pincer ligand 1 has been synthesized and chelated to manganese. The octahedral Mn(iv) bis(diiminosemiquinonate) and Mn(v) (diiminobenzoquinone) (diiminosemiquinonate) radicals were structurally characterized. read more here.
Keywords: pincer; species supported; bis; radical species ... See more keywords
Non-innocent redox behavior of CuII-p-dimethylaminophenolate complexes: formation and characterization of the CuI-phenoxyl radical species.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc01409b
Abstract: Cu complexes with p-dimethylaminophenolate ligands were synthesized by the reaction of CuII ions with the ligands under inert gas atmosphere and characterized. The complexes showed a valence state change from CuII-phenolate to CuI-phenoxyl radical on… read more here.
Keywords: cui phenoxyl; radical species; cuii; phenoxyl radical ... See more keywords
Systematic radical species control by electron push–pull substitution in the perylene-based D–π–A compounds
Sign Up to like & getrecommendations! Published in 2023 at "RSC Advances"
DOI: 10.1039/d2ra06460j
Abstract: Organic radical materials have been mainly reported on the stabilization of radical species because of their high energy and reactivity, while design strategies for controlling radical species beyond stabilization have remained challenging. Here, we report… read more here.
Keywords: radical species; perylene based; systematic radical; push pull ... See more keywords
Alkoxysulfonyl radical species: acquisition and transformation towards sulfonate esters through electrochemistry
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Science"
DOI: 10.1039/d2sc04027a
Abstract: Sulfonyl radical mediated processes have been considered as a powerful strategy for the construction of sulfonyl compounds. However, an efficient and high atom-economical radical approach to the synthesis of sulfonate esters is still rare, owing… read more here.
Keywords: alkoxysulfonyl radical; species acquisition; radical species; electrochemistry ... See more keywords
Fluid modeling of radical species generation mechanism in dense methane-air mixture streamer discharge
Sign Up to like & getrecommendations! Published in 2018 at "Physics of Plasmas"
DOI: 10.1063/1.5016855
Abstract: Atmospheric dielectric barrier discharge (DBD) was found to be promising in the context of plasma chemistry, plasma medicine, and plasma-assisted combustion. In this paper, we present a detailed fluid modeling study of abundant radical species… read more here.
Keywords: fluid modeling; dense methane; discharge; radical species ... See more keywords
Involvement of Nitric Oxide in Protecting against Radical Species and Autoregulation of M1-Polarized Macrophages through Metabolic Remodeling
Sign Up to like & getrecommendations! Published in 2023 at "Molecules"
DOI: 10.3390/molecules28020814
Abstract: When the expression of NOS2 in M1-polarized macrophages is induced, huge amounts of nitric oxide (•NO) are produced from arginine and molecular oxygen as the substrates. While anti-microbial action is the primary function of M1… read more here.
Keywords: oxide protecting; radical species; nitric oxide; polarized macrophages ... See more keywords