Radical Sulfimidation via Visible-Light Photoredox Catalysis: N-Acyloxyamides as Bench-Stable Nitrene Surrogates.
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DOI: 10.1021/acs.orglett.5c04127
Abstract: Herein, we describe a visible-light-driven sulfimidation of thioethers with N-acyloxyamides catalyzed by TPT. The protocol proceeds under ambient conditions, tolerates a broad range of functional groups, and delivers the desired products in yields of up… read more here.
Keywords: sulfimidation; radical sulfimidation; light photoredox; visible light ... See more keywords