Hyperbranched polymers with step-growth chemistries from transfer-dominated branching radical telomerisation (TBRT) of divinyl monomers
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DOI: 10.1039/d0py01309a
Abstract: The commercially relevant synthesis of novel materials with step-growth backbones has been achieved by applying conventional chemistries to the radical telomerisation of divinyl monomers leading to high molecular weight branched polymers. read more here.
Keywords: radical telomerisation; divinyl monomers; step growth;
Using temperature to modify the reaction conditions and outcomes of polymers formed using transfer-dominated branching radical telomerisation (TBRT)
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DOI: 10.1039/d2ra06578a
Abstract: Transfer-dominated Branching Radical Telomerisation (TBRT) enables the production of branched polymers with step-growth backbones using radical telomerisation chemistry. By conducting identical TBRTs over a broad temperature range, the role of temperature in telomer formation and… read more here.
Keywords: temperature; radical telomerisation; dominated branching; transfer dominated ... See more keywords