ART─An Amino Radical Transfer Strategy for C(sp2)-C(sp3) Coupling Reactions, Enabled by Dual Photo/Nickel Catalysis.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c03220
Abstract: Introducing the novel concept of amino radical transfer (ART) enables the use of easily accessible and commercially available alkyl boronic esters as cross-coupling partners for aryl halides in dual photoredox/nickel catalysis mediated by visible light.… read more here.
Keywords: radical transfer; sp2 sp3; nickel catalysis; amino radical ... See more keywords
Real-space investigations of on-surface intermolecular radical transfer reactions assisted by persistent radicals
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DOI: 10.1126/sciadv.adu9436
Abstract: Synthesizing radicals that have both long lifetimes and high chemical reactivity remains a long-term challenge. Here, persistent phenyl radicals are successfully synthesized on Ag(111) by protecting the carbon radical site by designing the precursor molecule… read more here.
Keywords: radical transfer; transfer reactions; space; persistent radicals ... See more keywords
Benzothiazolines Acting as Carbanion and Radical Transfer Reagents in Carbon–Carbon Bond Construction
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DOI: 10.3390/molecules30081711
Abstract: Traditionally employed as hydrogenation reagents, benzothiazolines have emerged as versatile carbanion and radical transfer reagents, playing a vital role in the construction of various carbon–carbon bonds. The cutting-edge progress in photochemistry and radical chemistry have… read more here.
Keywords: radical transfer; carbon; transfer reagents; carbon carbon ... See more keywords