Azodioxy compounds as precursors for C-radicals and their application in thermal styrene difunctionalization
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DOI: 10.1039/d2sc03860a
Abstract: An atom-economic thermal α,β-difunctionalization of various styrenes with readily prepared azodioxy compounds is reported. Mechanistic studies reveal that the starting azodioxy compounds can thermally be cleaved to the corresponding C-nitroso compounds, which under these thermal… read more here.
Keywords: styrene; difunctionalization; precursors radicals; azodioxy compounds ... See more keywords
Photoinduced Generation of Ketyl Radicals and Application in C−C Coupling without External Photocatalyst
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DOI: 10.1039/d3gc00054k
Abstract: Single-electron reduction of a carbonyl by photoredox catalysis enables generation of ketyl radical, providing a benign procedure to construct C−C bonds. However, external photocatalysts are required. In this paper, photoinduced... read more here.
Keywords: generation ketyl; photoinduced generation; generation; application coupling ... See more keywords