Reductive Radical Cascades Triggered by Alkoxyl Radicals in the β-Cyclodextrin Framework.
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DOI: 10.1021/acs.orglett.8b01308
Abstract: The generation and fate of 2I-VII,3I-VII,6II-VII-icosa- O-methyl-β-cyclomaltoheptaos-6I- O-yl radical under reductive conditions is described. Two radical cascade reactions are involved: the main one is triggered by a 1,8-HAT of the hydrogen at 5VIIC. The radical… read more here.
Keywords: radicals cyclodextrin; radical cascades; reductive radical; triggered alkoxyl ... See more keywords