Application of Pulse Radiolysis to Mechanistic Investigations of Catalysis Relevant to Artificial Photosynthesis.
Sign Up to like & getrecommendations! Published in 2017 at "ChemSusChem"
DOI: 10.1002/cssc.201701559
Abstract: Taking inspiration from natural photosystems, the goal of artificial photosynthesis is to harness solar energy to convert abundant materials, such as CO2 and H2 O, into solar fuels. Catalysts are required to ensure that the… read more here.
Keywords: mechanistic investigations; relevant artificial; pulse radiolysis; radiolysis ... See more keywords
PyRad: A software shell for simulating radiolysis with Qball package
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Computational Chemistry"
DOI: 10.1002/jcc.26509
Abstract: The assessment of the radiolytic stability of media is an important task in the fields of nuclear power engineering and radiochemistry. Such studies must be carried out in special laboratory conditions with the use of… read more here.
Keywords: radiolysis; software shell; chemistry; pyrad software ... See more keywords
Radiolysis products and degradation mechanism studies on di-1-methyl heptyl methyl phosphonate
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Radioanalytical and Nuclear Chemistry"
DOI: 10.1007/s10967-017-5543-0
Abstract: Di-1-methyl heptyl methyl phosphonate (DMHMP) is a promising alternative extractant for Th-U fuel reprocessing, in which the irradiation stability of extractant should be systematically studied. In this paper, the radiolysis products of DMHMP were analyzed… read more here.
Keywords: radiolysis products; heptyl methyl; radiolysis; methyl heptyl ... See more keywords
On the reactivity of aqueous radiolysis products towards carbon black used in in-situ radiation-synthesis of catalytic nanoparticles in graphite electrodes
Sign Up to like & getrecommendations! Published in 2021 at "Carbon"
DOI: 10.1016/j.carbon.2020.10.094
Abstract: Abstract Enhanced electrochemical performance of graphite electrodes can be achieved by incorporation of catalytic nanoparticles. One promising method for incorporation is in-situ radiation-synthesis where the radiolysis of water is used to drive the process of… read more here.
Keywords: carbon; towards carbon; carbon black; graphite electrodes ... See more keywords
Pulse Radiolysis Studies for Mechanism in Biochemical Redox Reactions.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical reviews"
DOI: 10.1021/acs.chemrev.8b00405
Abstract: Pulse radiolysis is a powerful method for generating highly reduced or oxidized species and free radicals. Combined with fast time-resolved spectroscopic measurement, we can monitor the reactions of intermediate species on time scales ranging from… read more here.
Keywords: radiolysis redox; pulse radiolysis; radiolysis; electron ... See more keywords
Understanding Complex Electron Radiolysis in Saline Solution by Big Data Analysis
Sign Up to like & getrecommendations! Published in 2022 at "ACS Omega"
DOI: 10.1021/acsomega.2c01010
Abstract: In this article, we developed a new method to analyze the complex chemical reactions induced by electron beam radiolysis based on big data analysis. At first, we built an element transport network to show the… read more here.
Keywords: saline solution; big data; radiolysis; data analysis ... See more keywords
A Model for Radiolysis in a Flowing-Water Target during High-Intensity Proton Irradiation
Sign Up to like & getrecommendations! Published in 2022 at "ACS Omega"
DOI: 10.1021/acsomega.2c03540
Abstract: At the Facility for Rare Isotope Beams (FRIB), interactions between heavy-ion beams and beam-dump water will create a wide variety of radionuclides which can be accessed by a technique known as “isotope harvesting”. However, irradiation… read more here.
Keywords: flowing water; intensity proton; water; radiolysis ... See more keywords
Self-radiolysis of tritiated water. 4. The scavenging effect of azide ions (N3−) on the molecular hydrogen yield in the radiolysis of water by 60Co γ-rays and tritium β-particles at room temperature
Sign Up to like & getrecommendations! Published in 2018 at "RSC Advances"
DOI: 10.1039/c7ra12397c
Abstract: The effect of the azide ion N3− on the yield of molecular hydrogen in water irradiated with 60Co γ-rays (∼1 MeV Compton electrons) and tritium β-electrons (mean electron energy of ∼7.8 keV) at 25 °C… read more here.
Keywords: hydrogen; water; chemistry; geometry ... See more keywords
Controllability of cupric particle synthesis by linear alcohol chain number as additive and pH control in cupric acetate solution using X-ray radiolysis.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of synchrotron radiation"
DOI: 10.1107/s1600577519010543
Abstract: Synthesis and immobilization of caltrop cupric particles onto a Si substrate using X-ray radiolysis directly from a liquid solution of Cu(COOCH3)2 is demonstrated. Caltrop cupric oxide particles are formed in the X-ray radiolysis of aqueous… read more here.
Keywords: ray radiolysis; alcohol chain; radiolysis; synthesis ... See more keywords
On the Mechanism of the Steady-State Gamma Radiolysis-Induced Scissions of the Phenyl-Vinyl Polyester-Based Resins
Sign Up to like & getrecommendations! Published in 2022 at "Frontiers in Chemistry"
DOI: 10.3389/fchem.2021.803347
Abstract: The major societal problem of polymeric waste necessitates new approaches to break down especially challenging discarded waste streams. Gamma radiation was utilized in conjunction with varying solvent environments in an attempt to discern the efficacy… read more here.
Keywords: state gamma; radiolysis; gamma radiolysis; mechanism steady ... See more keywords
Ultrafast Processes Occurring in Radiolysis of Highly Concentrated Solutions of Nucleosides/Tides
Sign Up to like & getrecommendations! Published in 2019 at "International Journal of Molecular Sciences"
DOI: 10.3390/ijms20194963
Abstract: Among the radicals (hydroxyl radical (•OH), hydrogen atom (H•), and solvated electron (esol−)) that are generated via water radiolysis, •OH has been shown to be the main transient species responsible for radiation damage to DNA… read more here.
Keywords: nucleosides tides; solutions nucleosides; ultrafast processes; radiolysis ... See more keywords