Beyond simple AB diblock copolymers: application of bifunctional and trifunctional RAFT agents to PISA in water
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Molecular Modeling"
DOI: 10.1002/marc.((insert
Abstract: The influence of the macro-RAFT agent architecture on the morphology of the self-assemblies obtained by aqueous RAFT dispersion polymerization in PISA is studied by comparing amphiphilic AB diblock, (AB)2 triblock and triarm-star shaped (AB)3 copolymers,… read more here.
Keywords: shaped copolymers; raft; star shaped; beyond simple ... See more keywords
Toward Electrochemically Mediated Reversible Addition–Fragmentation Chain-Transfer (eRAFT) Polymerization: Can Propagating Radicals Be Efficiently Electrogenerated from RAFT Agents?
Sign Up to like & getrecommendations! Published in 2019 at "Macromolecules"
DOI: 10.1021/acs.macromol.9b00112
Abstract: Electrochemistry provides easily tunable parameters for the preparation of well-defined polymers in a spatiotemporal controlled manner under mild conditions. This work discusses the requisites for an electrochemically mediated reversible addition–fragmentation chain-transfer (eRAFT) polymerization, in which… read more here.
Keywords: raft; electrochemically mediated; mediated reversible; reversible addition ... See more keywords
Comparative Study of Protein Aggregation Arrest by Zwitterionic Polysulfobetaines: Using Contrasting Raft Agents
Sign Up to like & getrecommendations! Published in 2019 at "ACS Omega"
DOI: 10.1021/acsomega.9b01409
Abstract: Protein aggregation has caused limitations in the study and development of protein-based biopharmaceuticals. We prepared different polysulfobetaine (poly-SPB) polymers via reversible addition fragmentation chain transfer (RAFT) polymerization. These polymers exhibited high efficiency in modulation of… read more here.
Keywords: polysulfobetaines using; aggregation; raft agents; protein aggregation ... See more keywords
Ab initio RAFT emulsion polymerization mediated by small cationic RAFT agents to form polymers with low molar mass dispersity
Sign Up to like & getrecommendations! Published in 2019 at "Polymer Chemistry"
DOI: 10.1039/c9py00893d
Abstract: We report on low molar mass cationic RAFT agents that provide predictable molar mass and low molar mass dispersities (Đm) in ab initio emulsion polymerization. read more here.
Keywords: cationic raft; raft; low molar; molar mass ... See more keywords