Selective incorporation of 5‐hydroxytryptophan blocks long range electron transfer in oxalate decarboxylase
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DOI: 10.1002/pro.4537
Abstract: Oxalate decarboxylase from Bacillus subtilis is a binuclear Mn‐dependent acid stress response enzyme that converts the mono‐anion of oxalic acid into formate and carbon dioxide in a redox neutral unimolecular disproportionation reaction. A π‐stacked tryptophan… read more here.
Keywords: hydroxytryptophan; long range; range electron; electron transfer ... See more keywords