LAUSR

Rapid, Mild, and Selective Ketone and Aldehyde Hydroboration/Reduction Mediated by a Simple Lanthanide Catalyst

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0 Published in 2017 at "ACS Catalysis"

DOI: 10.1021/acscatal.6b03332

Abstract: Rapid, clean hydroboration of ketones and aldehydes with HBpin is achieved using the homoleptic rare-earth catalyst La[N(SiMe3)2]3 (LaNTMS). The reaction employs low catalyst loadings (0.01–1 mol % LaNTMS), proceeds rapidly (>99% in 5 min) at… read more here.

Keywords: rapid mild; mild selective; catalyst; ketone aldehyde ... See more keywords