A potential case of the rare Cluster Core Isomerism for phosphido-bridged Pt3 units suggested by DFT calculations
Sign Up to like & getrecommendations! Published in 2018 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2017.09.068
Abstract: Abstract Triangular platinum clusters with phosphido bridging ligands and 44 valence electrons may adopt two structural types with either an equilateral or isosceles Pt 3 triangle, hence with a closed or an open ring formulation… read more here.
Keywords: rare cluster; core isomerism; cluster core; isomerism ... See more keywords
Enhanced Rishirilide Biosynthesis by a Rare In-Cluster Phosphopantetheinyl Transferase in Streptomyces xanthophaeus
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DOI: 10.1128/spectrum.03247-22
Abstract: Genome mining has been a vital means for natural product drug discovery in the postgenomic era. The rishirilide-type polyketides have attracted attention due to their potent bioactivity, but the poor robustness of production hosts has… read more here.
Keywords: biosynthesis; cluster; streptomyces xanthophaeus; rishirilide biosynthesis ... See more keywords