Accelerated tert-butyloxycarbonyl deprotection of amines in microdroplets produced by a pneumatic spray
Sign Up to like & getrecommendations! Published in 2018 at "International Journal of Mass Spectrometry"
DOI: 10.1016/j.ijms.2018.05.009
Abstract: Abstract Protection and deprotection of organic compounds in multistep reactions using functional groups such as tert-butoxycarbonyl (Boc), is widely performed in synthetic organic chemistry. Reaction rate acceleration studies in spray-based ionization methods (electrosonic spray, paper… read more here.
Keywords: spray; rate acceleration; deprotection; reaction ... See more keywords
Source of Rate Acceleration for Carbocation Cyclization in Biomimetic Supramolecular Cages.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c04179
Abstract: The results of quantum chemical and molecular dynamics calculations reveal that polyanionic gallium-based cages accelerate cyclization reactions of pentadienyl alcohols as a result of substrate cage interactions, preferential binding of reactive conformations of substrate/H3O+ pairs,… read more here.
Keywords: source rate; acceleration carbocation; rate acceleration; cyclization ... See more keywords