Thermodynamically consistent forward and reverse degrees of rate control in reversible reactions
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Catalysis"
DOI: 10.1016/j.jcat.2020.06.013
Abstract: Abstract The net rate of a composite reaction is the difference between the forward and reverse reaction rates, which are kinetically distinct despite sharing elementary reaction steps and therefore have different rate-controlling transition states and… read more here.
Keywords: state; forward reverse; reaction; rate ... See more keywords
A novel degradation rate controlling mechanism of biocompatible Mg-Zn-Y-Zr alloys
Sign Up to like & getrecommendations! Published in 2019 at "Materials Letters"
DOI: 10.1016/j.matlet.2018.09.165
Abstract: Abstract Aiming to develop a possible approach to precisely control the degradation rate of long period stacking order (LPSO) structured Mg-Zn-Y-Zr alloys in NaCl solution, this work investigates the degradation behavior and the relation between… read more here.
Keywords: controlling mechanism; degradation; degradation rate; rate controlling ... See more keywords
Amphiphilic Nanoparticle-in-Nanoparticle Drug Delivery Systems Exhibiting Cross-Linked Inorganic Rate-Controlling Domains
Sign Up to like & getrecommendations! Published in 2017 at "Chemistry of Materials"
DOI: 10.1021/acs.chemmater.6b04922
Abstract: Aiming to explore the potential of sol–gel chemistry to physically stabilize polymeric micelles and confer sustained release features, this work reports for the first time on the production of hybrid organic–inorganic multimicellar nanomaterials that, as… read more here.
Keywords: cross linked; chemistry; controlling domains; rate controlling ... See more keywords
Rate Controlling in Low-Temperature Standard NH3-SCR: Implications from Operando EPR Spectroscopy and Reaction Kinetics.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c01933
Abstract: A series of seven Cu/SSZ-13 catalysts with Si/Al = 6.7 are used to elucidate key rate-controlling factors during low-temperature standard ammonia-selective catalytic reduction (NH3-SCR), via a combination of SCR kinetics and operando electron paramagnetic resonance… read more here.
Keywords: rate controlling; low temperature; spectroscopy; epr spectroscopy ... See more keywords