Second-Sphere Hydrogen-Bond Donors and Acceptors Affect the Rate and Selectivity of Electrochemical Oxygen Reduction by Iron Porphyrins Differently.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c02170
Abstract: The factors that control the rate and selectivity of 4e-/4H+ O2 reduction are important for efficient energy transformation as well as for understanding the terminal step of respiration in aerobic organisms. Inspired by the design… read more here.
Keywords: hydrogen bond; rate selectivity; second sphere; rate ... See more keywords
Rate and selectivity hysteresis during the carbon monoxide hydrogenation over promoted Co/MnOx catalysts
Sign Up to like & getrecommendations! Published in 2019 at "Nature Communications"
DOI: 10.1038/s41467-019-11836-z
Abstract: While cobalt-based catalysts have been used in industrial Fischer-Tropsch synthesis for decades, little is known about how the dynamics of the Co-Co2C phase transformation drive their performance. Here we report on the occurrence of hysteresis… read more here.
Keywords: hysteresis; selectivity; rate selectivity; carbon monoxide ... See more keywords