Lone-Pair-Induced Structural Ordering in the Mixed-Valent 0D Metal-Halides Rb23BiIIIxSbIII7–xSbV2Cl54 (0 ≤ x ≤ 7)
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DOI: 10.1021/acs.chemmater.0c04491
Abstract: Mixed-valent metal-halides containing ns2 lone pairs may exhibit intense visible absorption, while zero-dimensional (0D) ns2-based metal-chlorides are generally colorless but have demonstrated promising optoelectronic properties suitable for thermometry and radiation detection. Here, we report solvothermally… read more here.
Keywords: rb23biiiixsbiii7 xsbv2cl54; metal; valent metal; metal halides ... See more keywords