Formyl C-H activation in N,N-Dimethylformamide by a dirhenium carbonyl complex
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DOI: 10.1016/j.jorganchem.2017.03.009
Abstract: Abstract The reaction of Re2(CO)8[μ-η2-C(H)=C(H)Bun](μ-H), 1 with N,N-dimethylformamide (DMF) at 70 C for 6 h has yielded three new compounds: Re2(CO)8(μ-η2-O=CNMe2)(μ-H), 2, (16% yield), Re2(CO)7(NHMe2)(μ-η2-O=CNMe2)(μ-H), 3, (30% yield), Re2(CO)9(NHMe2), 4 (14% yield). Compounds 2 and 3 contain… read more here.
Keywords: re2; compound; reaction; yield ... See more keywords
Coordination chemistry of thioether-carboranes in polynuclear metal carbonyl cluster complexes. B-H activation of thioether-carboranes by dirhenium carbonyl complexes
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2017.09.004
Abstract: Abstract Two new dirhenium compounds Re2(CO)8[μ-η2-1,3-C2B10H10(1-SCH3)](μ-H), 1 (3.2 % yield) and Re2(CO)8[μ-η2-1,4-C2B10H10(1-SCH3)](μ-H), 2 (31 % yield) were obtained from the reaction of closo-o-(1-SCH3)C2B10H11 with Re2(CO)8[μ-η2-C(H)C(H)Bun](μ-H) in an octane solution heated to reflux. Both compounds contain… read more here.
Keywords: re2; thioether carboranes; chemistry; sch3 ... See more keywords
The activation and transformations of vinyl acetate at a dirhenium carbonyl center
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2019.120969
Abstract: Abstract The reaction of Re2(CO)8(μ-C6H5)(μ-H), 1 with vinyl acetate in methylene chloride by heating at 40 °C yielded three new products: Re3(CO)13(μ-η2-C2H3), 3, (24% yield), Re2(CO)8(μ-η2-O2CCH3)(μ-H), 4, (9% yield) and Re2(CO)8(μ-η2-CHCHO2CCH3)(μ-H), 5, (13% yield). Compound 3… read more here.
Keywords: re2; vinyl acetate; yield; compound ... See more keywords
Synthesis and Chemistry of Ammonioethenyl and Phosphonioethenyl Ligands in Zwitterionic Dirhenium Carbonyl Complexes.
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DOI: 10.1021/acs.inorgchem.2c01471
Abstract: New zwitterionic dirhenium carbonyl complexes containing ammonioethenyl and phosphonioethenyl ligands have been synthesized and studied. The reaction of Re2(CO)10 with C2H2 and Me3NO yielded the dirhenium complex Re2(CO)9(NMe3) (6) and the new zwitterionic complex Re2(CO)9[η1-E-2-CH═CH(NMe3)]… read more here.
Keywords: dirhenium carbonyl; re2; carbonyl complexes; chemistry ... See more keywords