Enantioselective Oxidative Ring-Opening Reaction of Aziridines with α-Nitroesters Using Cinchona Alkaloid Amide/Nickel(II) Catalysts.
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DOI: 10.1021/acs.orglett.6b03346
Abstract: The enantioselective oxidative ring-opening reaction of aziridines with α-nitroacetates has been developed. Good yields and enantioselectivity were observed for the reaction of various aziridines using a novel cinchona alkaloid amide/NiBr2 catalyst. Both enantiomers of products… read more here.
Keywords: enantioselective oxidative; ring opening; oxidative ring; reaction ... See more keywords