Divergent synthesis of functionalized thioethers via multicomponent reaction of benzynes
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DOI: 10.1016/j.tet.2018.04.072
Abstract: Abstract Diverse functionalized thioethers were efficiently synthesized through the multicomponent reaction of benzynes, cyclic thioethers and different nucleophiles. Both inorganic salts (KF, KCl, KBr, and KSCN) and silylated reagents (TMSCN, TMSN3, TMSCl) can be utilized… read more here.
Keywords: divergent synthesis; multicomponent reaction; functionalized thioethers; synthesis functionalized ... See more keywords
Transition-metal-free synthesis of aromatic amines via the reaction of benzynes with isocyanates
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DOI: 10.1016/j.tetlet.2018.01.022
Abstract: Abstract An unexpected reaction between benzynes and isocyanates to generate aromatic amines has been developed under transition-metal-free conditions. The in situ prepared anions formed through cleavage of the N C bond in isocyanates, reacted with… read more here.
Keywords: transition metal; aromatic amines; benzynes isocyanates; reaction benzynes ... See more keywords