C-Ni bond functionalization in the reaction of binuclear cyclometallated Ni(II) complexes with chlorophosphines
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DOI: 10.1016/j.jscs.2020.101178
Abstract: Abstract This manuscript reports successful C-H nickellation of the aryl phosphinites (i-Pr2P(O-aryl) derived from un-substituted/substituted phenols: C6H5OH, 4-R-C6H4OH (R = F, MeO). Nickellation was observed with the phosphinites at an ortho-C-H position to generate Br-bridged dimers [{κP,κC-(i-Pr)2PO-aryl}cNi(μ-Br)]2… read more here.
Keywords: bond functionalization; reaction binuclear; functionalization reaction; reaction ... See more keywords