Insertion Reaction of 2-Halo-N-allylanilines with K2S Involving Trisulfur Radical Anion: Synthesis of Benzothiazole Derivatives under Transition-Metal-Free Conditions
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DOI: 10.1055/s-0040-1706104
Abstract: A synthesis of benzothiazole derivatives through the reaction of 2-halo-N-allylanilines with K2S in DMF is developed. The trisulfur radical anion S3·–, which is generated in situ from K2S in DMF, initiates the reaction without transition-metal… read more here.
Keywords: benzothiazole; synthesis benzothiazole; reaction halo; benzothiazole derivatives ... See more keywords