Mass Spectrometric and Vibrational Characterization of Reaction Intermediates in [Ru(bpy)(tpy)(H2 O)]2+ Catalyzed Water Oxidation.
Sign Up to like & getrecommendations! Published in 2017 at "ChemPlusChem"
DOI: 10.1002/cplu.201700085
Abstract: Mass spectrometry coupled with an in-line electrochemical electrospray ionization source is used to capture some of the reaction intermediates formed in the [Ru(bpy)(tpy)(H2 O)]2+ (bpy=2,2'-bipyridine, tpy=2,2':6',2"-terpyridine) catalyzed water oxidation reaction. By controlling the applied electrochemical… read more here.
Keywords: bpy tpy; catalyzed water; reaction intermediates; oxidation ... See more keywords
Methanation of CO2 over nickel catalysts: Impacts of acidic/basic sites on formation of the reaction intermediates
Sign Up to like & getrecommendations! Published in 2020 at "Fuel"
DOI: 10.1016/j.fuel.2019.116521
Abstract: Abstract Methanation of carbon oxides is an important route to produce synthetic gas for civil use. Understanding acidic/basic properties of catalyst on the reaction intermediates in methanation provides important information for developing highly active catalysts.… read more here.
Keywords: reaction intermediates; basic sites; acidic basic; co2 ... See more keywords
Impacts of residence time on transformation of reaction intermediates and coking behaviors of acetic acid during steam reforming
Sign Up to like & getrecommendations! Published in 2021 at "Journal of The Energy Institute"
DOI: 10.1016/j.joei.2021.01.004
Abstract: Abstract Liquid hourly space velocity (LHSV) is a critical factor in steam reforming as it not only determines process capacity of reformer, but also affect the properties of the coke formed via impacting the activation… read more here.
Keywords: reaction intermediates; acetic acid; steam reforming; residence time ... See more keywords
Interaction of the reaction intermediates in co-reforming of acetic acid and ethanol impacts coke properties
Sign Up to like & getrecommendations! Published in 2021 at "Molecular Catalysis"
DOI: 10.1016/j.mcat.2021.111461
Abstract: Abstract Bio-oil is a mixture of organics and its steam reforming for production of hydrogen has attracted extensive attention. During steam reforming, the reaction intermediates derived from the varied organics in bio-oil might interact with… read more here.
Keywords: acetic acid; steam reforming; reaction intermediates; acid ethanol ... See more keywords
First-Generation Organic Reaction Intermediates in Zeolite Chemistry and Catalysis.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical reviews"
DOI: 10.1021/acs.chemrev.2c00076
Abstract: Zeolite chemistry and catalysis are expected to play a decisive role in the next decade(s) to build a more decentralized renewable feedstock-dependent sustainable society owing to the increased scrutiny over carbon emissions. Therefore, the lack… read more here.
Keywords: catalysis; chemistry catalysis; chemistry; zeolite chemistry ... See more keywords
Identifying Surface Reaction Intermediates in Plasma Catalytic Ammonia Synthesis
Sign Up to like & getrecommendations! Published in 2020 at "ACS Catalysis"
DOI: 10.1021/acscatal.0c03166
Abstract: Ammonia synthesis by plasma catalysis has emerged as an alternative process for decoupling nitrogen fixation from fossil fuels. Plasma activation can potentially circumvent the limitations of conve... read more here.
Keywords: reaction intermediates; intermediates plasma; ammonia synthesis; identifying surface ... See more keywords
Enriching Reaction Intermediates in Multishell Structured Copper Catalysts for Boosted Propanol Electrosynthesis from Carbon Monoxide.
Sign Up to like & getrecommendations! Published in 2023 at "ACS nano"
DOI: 10.1021/acsnano.3c01516
Abstract: Fine-tuned catalysts that alter the diffusion kinetics of reaction intermediates is of great importance for achieving high-performance multicarbon (C2+) product generation in carbon monoxide (CO) reduction. Herein, we conduct a structural design based on Cu2O… read more here.
Keywords: multishell structured; propanol electrosynthesis; reaction intermediates; carbon monoxide ... See more keywords
Practical Synthesis of Functionalized Chromeno[3,4-c]pyridine Derivatives via a CuCl2-Catalyzed Tandem Reaction of the Blaise Reaction Intermediates and 3-Cyanocoumarins
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DOI: 10.1055/s-0036-1591535
Abstract: This work discloses a novel and efficient protocol for the construction of functionalized chromeno[3,4-c]pyridine derivatives from the Blaise reaction intermediates and 3-cyanocoumarins through a CuCl2-catalyzed sequential Michael addition/intramolecular cyclization/oxidative aromatization reaction. This new method shows… read more here.
Keywords: reaction intermediates; blaise reaction; functionalized chromeno; chromeno pyridine ... See more keywords
Vinylidene ortho-Quinone Methides: Unique Chiral Reaction Intermediates in Catalytic Asymmetric Synthesis.
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DOI: 10.2533/chimia.2018.892
Abstract: Vinylidene ortho-quinone methides (VQMs) are one-carbon elongated homologues of ortho-quinone methides (QMs), well-known as useful reaction intermediates in organic transformations. These related quinone methides are quite distinct in terms of stereochemistry. Namely, VQMs are characterized… read more here.
Keywords: ortho quinone; reaction intermediates; vinylidene ortho; quinone methides ... See more keywords
Deamination of 1-Aminoalkylphosphonic Acids: Reaction Intermediates and Selectivity
Sign Up to like & getrecommendations! Published in 2022 at "Molecules"
DOI: 10.3390/molecules27248849
Abstract: Deamination of 1-aminoalkylphosphonic acids in the reaction with HNO2 (generated “in situ” from NaNO2) yields a mixture of substitution products (1-hydroxyalkylphosphonic acids), elimination products (vinylphosphonic acid derivatives), rearrangement and substitution products (2-hydroxylkylphosphonic acids) as well… read more here.
Keywords: reaction; aminoalkylphosphonic acids; deamination; reaction intermediates ... See more keywords