Synthesis of Organic Super-Electron-Donors by Reaction of Nitrous Oxide with N-Heterocyclic Olefins.
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DOI: 10.1021/jacs.9b10660
Abstract: The reaction of nitrous oxide (N2O) with N-heterocyclic olefins (NHOs) results in cleavage of the N-O bond and formation of azo-bridged NHO dimers. The latter represent very electron-rich compounds with a low ionization energy. Cyclic… read more here.
Keywords: reaction nitrous; nitrous oxide; electron; super electron ... See more keywords