Facile Access to Cyclopentadienes via Catalytic Intramolecular Palladium-Ene Reaction of 2,4-Pentadienyl Acetates
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DOI: 10.1055/s-0037-1610552
Abstract: We have recently disclosed a palladium-catalyzed Trost–Oppolzer type Alder-ene reaction of 2,4-pentadienyl acetates for the synthesis of highly substituted cyclopentadienes and cyclopentene-fused aromatics. The overall transformation also represents an acid-free iso-Nazarov type cyclization. Herein, we… read more here.
Keywords: reaction pentadienyl; palladium; pentadienyl acetates; ene reaction ... See more keywords