Mechanistic and kinetic study on the reaction of Pyrrole (C4H5N) with O(3P)
Sign Up to like & getrecommendations! Published in 2018 at "Chemical Physics"
DOI: 10.1016/j.chemphys.2018.06.019
Abstract: Abstract The mechanism and kinetic for the reaction of Pyrrole + O(3P) has been investigated using CCSD(T)//M06-2X method with multichannel RRKM-TST calculation. On the triplet surface, four product channels corresponding to α-C-addition, β-C-addition, N-addition and direct H-abstraction… read more here.
Keywords: pyrrole; study reaction; reaction pyrrole; kinetic study ... See more keywords
Mannich reaction of pyrrole and dimethylpyrrole with monoamines and diamines
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DOI: 10.1016/j.tetlet.2019.151247
Abstract: Abstract The Mannich reaction of pyrrole with ethylenediamine dihydrochloride and formaldehyde gave two compounds: N1,N1,N2,N2-tetrakis(pyrrol-2-ylmethyl)ethane-1,2-diamine 1 and 1,3-bis(pyrrol-2-ylmethyl)imidazolidine 2 in poor yields. Conversely, the reaction of pyrrole with propylenediamine dihydrochloride afforded macrocyclic compound 3 containing… read more here.
Keywords: pyrrole dimethylpyrrole; mannich reaction; reaction; reaction pyrrole ... See more keywords