Synthesis of 2‐Substituted 2‐Amino Ketones by Rhodium‐Catalyzed Reaction of N‐Sulfonyl‐1,2,3‐triazoles with 2‐Alkenols
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DOI: 10.1002/hlca.201600320
Abstract: A study on a rhodium(II)-catalyzed reaction of N-sulfonyl-1,2,3-triazoles with 2-alkenols is reported. The reaction is initiated by insertion of an α-imino carbene into the O–H linkage of alcohol, forming a 2-alkenoxy enamide intermediate. A thermal… read more here.
Keywords: triazoles alkenols; reaction sulfonyl; rhodium catalyzed; sulfonyl triazoles ... See more keywords