Formation and reactions of active five-membered phosphane/borane frustrated Lewis pair ring systems.
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DOI: 10.1039/c8dt00672e
Abstract: The reactive five-membered frustrated P/B Lewis pair 6a was generated from Tipp-P(vinyl)2 (Tipp: 2,4,6-triisopropylphenyl) by a series of anti-Markovnikov and Markovnikov hydroboration reactions. The in situ generated compound dimerized to give 7a under kinetic control… read more here.
Keywords: reactions active; pair; lewis pair; formation reactions ... See more keywords