Nucleophile induced ligand rearrangement reactions of alkoxy- and arylsilanes
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DOI: 10.1016/j.tet.2019.04.062
Abstract: Abstract The ligand-redistribution reactions of aryl- and alkoxy-hydrosilanes can potentially cause the formation of gaseous hydrosilanes, which are flammable and pyrophoric. The ability of generic nucleophiles to initiate the ligand-redistribution reaction of commonly used hydrosilane… read more here.
Keywords: induced ligand; reactions alkoxy; ligand rearrangement; ligand redistribution ... See more keywords