Platinum-catalyzed reactions of 2,3-bis(dimethylsilyl)furan with alkynes
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2017.10.016
Abstract: Abstract The synthesis and platinum-catalyzed reactions of 2,3-bis(dimethylsilyl)furan (1) have been reported. The reactions of 1 with diphenylacetylene and phenyl(trimethylsilyl)acetylene in the presence of a platinum catalyst gave the corresponding six-membered ring compounds produced from… read more here.
Keywords: platinum catalyzed; catalyzed reactions; reactions bis; dimethylsilyl furan ... See more keywords
Stereodivergent Photoelectrocyclization Reactions of Bis-aryl Cycloalkenones: Intercepting Photoelectrocyclization Intermediates with Acid.
Sign Up to like & getrecommendations! Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.9b03214
Abstract: Described here are tandem photoelectrocyclization and [1,5]-hydride shift reactions of heteroaryl-containing bis-aryl cyclohexenone derivatives that give heteroaryl-substituted dihydrophenanthrenes. This Letter demonstrates that electrocyclization intermediates can be trapped with acid when the [1,5]-hydride shift is relatively… read more here.
Keywords: bis aryl; reactions bis; photoelectrocyclization reactions; stereodivergent photoelectrocyclization ... See more keywords