Reactions of Cyclic Osmacarbyne with Coinage Metal Complexes
Sign Up to like & getrecommendations! Published in 2018 at "Organometallics"
DOI: 10.1021/acs.organomet.8b00214
Abstract: The reactions of the five-membered cyclic osmacarbyne complex, i.e., osmapentalyne, with a complete set of coinage metal (Cu, Ag, and Au) complexes have been investigated. Osmapentalyne 1 reacts with CuCl or AuCl(PPh3) via its metal–carbon… read more here.
Keywords: coinage metal; reactions cyclic; metal; metal complexes ... See more keywords
Unprecedented Elimination Reactions of Cyclic Aldols: A New Biosynthetic Pathway toward the Taiwaniaquinoid Skeleton
Sign Up to like & getrecommendations! Published in 2023 at "Molecules"
DOI: 10.3390/molecules28041524
Abstract: The acid treatment of 6,7-seco-abietane dialdehydes gives, in high yield, the corresponding derivatives with the 4a-methyltetrahydrofluorene skeleton of taiwaniaquinoids. A mechanism involving the elimination of formic acid from the cyclic aldol intermediate is proposed here.… read more here.
Keywords: cyclic aldols; reactions cyclic; unprecedented elimination; elimination reactions ... See more keywords