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Published in 2018 at "Synlett"
DOI: 10.1055/s-0037-1610339
Abstract: Pd-catalyzed C–H silylation reactions remain underdeveloped. General strategies usually rely on the use of complex bidentate directing groups. C,C-Palladacycles exhibit extremely high reactivity towards hexamethyldisilane and can be disilylated very efficiently. The C,C-palladacycles are prepared…
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Keywords:
silylation;
reactions disilanes;
palladacycles generated;
catalyzed silylation ... See more keywords