Regioselectivity in C–H activation: Reactions of N-heterocyclic indenes with Ru3(CO)12
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DOI: 10.1016/j.poly.2018.11.017
Abstract: Abstract Thermal treatment of Ru3(CO)12 with 3-(6-ethyl-2-pyridyl)indene in refluxing toluene gave a triruthenium carbonyl complex {μ2-η5:η1-(C2H5C5H4N)(C9H5)}Ru3(CO)9 (1) via regioselective C(sp2)–H activation. While reaction of 2-methyl-3-(6-ethyl-2-pyridyl)indene with Ru3(CO)12 generated a dinuclear ruthenium complex {(C2H5C5H4N)(μ2-η5,η1-C9H5CH2)}Ru2(CO)5 (2) via… read more here.
Keywords: activation; reactions heterocyclic; regioselectivity activation; indenes ru3 ... See more keywords
Reactions of N-heterocyclic carbene-based chalcogenoureas with halogens: a diverse range of outcomes.
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DOI: 10.1039/d2dt00010e
Abstract: We have investigated the reactions of chalcogenoureas derived from N-heterocyclic carbenes, referred to here as [E(NHC)], with halogens. Depending on the structure of the chalcogenourea and the identity of the halogen, a diverse range of… read more here.
Keywords: based chalcogenoureas; carbene based; reactions heterocyclic; diverse range ... See more keywords