Reactions of Rh(PNP) pincer complexes with terminal alkynes: homocoupling through a ring or not at all.
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DOI: 10.1039/d0dt03550e
Abstract: Through use of a bespoke macrocyclic variant, we demonstrate a novel approach for tuning the reactivity of rhodium PNP pincer complexes that enables formation of conjugated enynes from terminal alkynes, rather than vinylidene derivates. This… read more here.
Keywords: pnp pincer; terminal alkynes; reactions pnp; complexes terminal ... See more keywords